4-(5-Chloro-2-hydroxybenzylideneamino)-N-(4,6-dimethylpyrimidin-2-yl)benzenesulfonamide

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N′-(5-Chloro-2-hydroxy­benzyl­idene)-4-hydroxy­benzohydrazide

The title Schiff base compound, C(14)H(11)ClN(2)O(3), was prepared by the reaction of 5-chloro-salicylaldehyde and 4-hydroxy-benzohydrazide. The mol-ecule exists in a trans configuration with respect to the methyl-idene group. The dihedral angle between the two benzene rings is 40.1 (2)°. An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular conformation. In the crystal struc...

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N′-(5-Chloro-2-hy­droxy­benzyl­idene)-4-meth­oxy­benzohydrazide

The asymmetric unit of the title compound, C(15)H(13)ClN(2)O(3), contains two independent hydrazone mol-ecules. Each mol-ecule adopts an E configuration with respect to the methyl-idene unit and forms an intra-molecular O-H⋯N hydrogen bond. The principal difference between the two unique mol-ecules is the relative orientation of the two benzene rings, the dihedral angles between them being 4.0 ...

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4-Chloro-N′-(5-chloro-2-hydroxy­benzyl­idene)benzohydrazide

The mol-ecule of the title compound, C(14)H(10)Cl(2)N(2)O(2), displays a trans configuration with respect to the C=N double bond and has an intramolecular O-H⋯N hydrogen bond. The dihedral angle between the two benzene rings is 1.4 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the a direction.

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2-Chloro-N-[4-chloro-2-(2-chloro­benzo­yl)phen­yl]acetamide

In the title compound, C(15)H(10)Cl(3)NO(2), an intra-molecular N-H⋯O hydrogen bond forms a six-membered ring and enforces an almost coplanar conformation for the acetamido group, the central benzene ring and the bridging carbonyl C-C(=O)-C group: the dihedral angles between the benzene ring and the acetamide and carbonyl C-C(=O)-C planes are 7.06 (11) and 7.17 (12)°, respectively. The dihedral...

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N′-(5-Chloro-2-hy­droxy­benzyl­idene)-2-meth­oxy­benzohydrazide

The title Schiff base compound, C(15)H(13)ClN(2)O(3), was prepared by the reaction of equimolar quanti-ties of 5-chloro-2-hy-droxy-benzaldehyde with 2-meth-oxy-benzohydrazide in a methanol solution. The dihedral angle between the two benzene rings is 20.6 (3)°. An intra-molecular O-H⋯N hydrogen bond may influence the mol-ecular conformation. In the crystal structure, mol-ecules form chains alon...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808005606